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Syngas to gasoline plus
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Syngas to gasoline plus : ウィキペディア英語版
Syngas to gasoline plus

Syngas to gasoline plus (STG+) is a thermochemical process to convert natural gas, other gaseous hydrocarbons or gasified biomass into drop-in fuels, such as gasoline, diesel fuel or jet fuel, and organic solvents.
== Process chemistry ==

This process follows four principal steps in one continuous integrated loop, comprising four fixed bed reactors in a series in which a syngas is converted to synthetic fuels. The steps for producing high-octane synthetic gasoline are as follows:〔(Introduction to STG+ Technology ) ''Primus Green Energy'', February 2013. Retrieved: 5 March 2013.〕
* Methanol Synthesis: Syngas is fed to Reactor 1, the first of four reactors, which converts most of the syngas to methanol when passing through the catalyst bed.
CO + 2 H2 → CH3OH (methanol)
* Dimethyl Ether (DME) Synthesis: The methanol-rich gas from Reactor 1 is next fed to Reactor 2, the second STG+ reactor. The methanol is exposed to a catalyst and much of it is converted to DME, which involves a dehydration from methanol to form DME.
2 CH3OH → CH3OCH3 + H2O
* Gasoline synthesis: The Reactor 2 product gas is next fed to Reactor 3, the third reactor containing the catalyst for conversion of DME to hydrocarbons including paraffins (alkanes), aromatics, naphthenes (cycloalkanes) and small amounts of olefins (alkenes), typically with the carbon number ranging from 6 to 10.
* Gasoline Treatment: The fourth reactor provides transalkylation and hydrogenation treatment to the products coming from Reactor 3. The treatment reduces durene/isodurene (tetramethylbenzenes) and trimethylbenzene components that have high freezing points and must be minimized in gasoline. As a result, the synthetic gasoline product has high octane and desirable viscometric properties.
* Separator: Finally, the mixture from Reactor 4 is condensed to obtain gasoline. The non-condensed gas and gasoline are separated in a conventional condenser/separator. Most of the non-condensed gas from the product separator becomes recycled gas and is sent back to the feed stream to Reactor 1, leaving the synthetic gasoline product composed of paraffins, aromatics and naphthenes.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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